Might want to skip the first minute or two as it's mostly just shredding and wankery. Dude has some serious chops. Song starts around 2:45. All sorts of good shit past the 4min mark.
[VIDEO]http://www.youtube.com/watch?v=09HyCVGZaGM]YouTube - Guitar Center Sessions: John 5 - Part 1[/VIDEO]
I dig the hell out of the bit that starts at 5:55. (Though I can't say I'm a fan of his guitar tone)
great playing, horrible tone. i'm still amazed he can shred like this on a tele